Statistical definition of entropy relating to the number of microstates of a system.Boltzmann entropy is a statistical mechanics definition of entropy that quantifies the number of microscopic configurations (microstates) consistent with a given macroscopic state (macrostate). It is expressed as S = k_B ln W, where k_B is Boltzmann's constant and W is the number of microstates. This definition provides a probabilistic foundation for the second law of thermodynamics, explaining why entropy tends to increase: systems naturally evolve toward macrostates with the largest number of microstates.
Ludwig Boltzmann introduced this statistical interpretation of entropy in the 1870s, building on the work of James Clerk Maxwell. His ideas were controversial at the time but became foundational for statistical mechanics.
The entropy is computed by counting all possible arrangements of particles (positions, momenta, spins, etc.) that yield the same macroscopic properties like temperature, pressure, and volume. The logarithm of this count, multiplied by Boltzmann's constant, gives the entropy. This approach connects the microscopic laws of physics to macroscopic thermodynamic behavior, and it underlies the concept of equilibrium as the most probable state.
It is used in computational physics to simulate thermodynamic systems, in information theory to define entropy, and in cosmology to discuss the arrow of time and the initial low-entropy state of the universe.
Boltzmann's entropy formula is engraved on his tombstone in Vienna, a testament to its central role in physics.






