
The symmetry properties of a crystal lattice that determine its physical properties.Crystal symmetry refers to the set of spatial symmetries—such as translations, rotations, reflections, and inversions—that leave a crystal lattice invariant. These symmetries are not just mathematical curiosities; they dictate many physical properties of crystals, including their optical behavior, electrical conductivity, and mechanical strength. For example, the arrangement of atoms in a crystal determines whether it is a conductor, semiconductor, or insulator, and whether it exhibits piezoelectricity or birefringence. The study of crystal symmetry is fundamental to solid-state physics and materials science.
The classification of crystal symmetries was developed in the late 19th century. Auguste Bravais identified the 14 possible lattice types in 1850, and the complete enumeration of the 230 space groups was achieved independently by Evgraf Fedorov (1891) and Arthur Schoenflies (1891).
A crystal is a periodic arrangement of atoms, and its symmetry is described by one of 230 possible space groups, which combine translational symmetry (the lattice) with point group symmetries (rotations, reflections, inversions). The symmetry operations constrain the possible positions of atoms and the tensor properties of the crystal, such as its elastic constants or dielectric tensor. For instance, a crystal with inversion symmetry cannot be piezoelectric, because the effect would cancel out under inversion. Symmetry also determines the selection rules for how light interacts with the crystal, such as which vibrational modes are infrared-active or Raman-active.
Crystal symmetry is used in X-ray crystallography to determine the atomic structure of materials, in the design of semiconductors and lasers, and in the development of nonlinear optical crystals for frequency conversion.
Quasicrystals, discovered in 1982 by Dan Shechtman, have symmetries that are forbidden for ordinary crystals, such as five-fold rotational symmetry, and their discovery led to a paradigm shift in crystallography and a Nobel Prize in Chemistry in 2011.








