Superconductivity that cannot be explained by the conventional BCS theory, often involving more complex pairing mechanisms.Unconventional superconductivity refers to materials that superconduct — conduct electricity with zero resistance — but whose behavior cannot be explained by the standard BCS theory, which successfully describes conventional superconductors like lead or aluminum. In BCS theory, electrons form pairs (Cooper pairs) via vibrations of the crystal lattice (phonons), and these pairs condense into a single quantum state. Unconventional superconductors, such as high-temperature cuprates, iron-based superconductors, and heavy-fermion systems, exhibit pairing mechanisms that are not phonon-mediated, often involving magnetic fluctuations or other exotic interactions. These materials typically have higher critical temperatures (the temperature below which they superconduct) than conventional ones, and their properties challenge our understanding of quantum matter.
The concept emerged in the late 1970s and 1980s with the discovery of heavy-fermion superconductors (e.g., CeCu2Si2 in 1979) and later the high-temperature cuprates in 1986 by Bednorz and Müller. The term 'unconventional' was coined to distinguish these from BCS-type superconductors.
In unconventional superconductors, the electron pairing is not mediated by lattice vibrations. Instead, the pairing glue is often thought to be magnetic spin fluctuations — the collective motion of electron spins in the material. This leads to a different symmetry of the superconducting order parameter (the wavefunction describing the paired state). For example, in high-temperature cuprates, the pairing has 'd-wave' symmetry, meaning the probability of pairing depends on the direction of electron momentum, unlike the 's-wave' symmetry of conventional superconductors. The exact mechanism is still an active area of research, and it may vary between different families of unconventional superconductors.
Unconventional superconductors are used in research to explore quantum phenomena and have potential for high-field magnets, power transmission, and quantum computing, though practical applications are limited by the difficulty of fabricating these materials.
Some unconventional superconductors, like certain cuprates, superconduct at temperatures above the boiling point of liquid nitrogen (−196°C), making them much easier to cool than conventional superconductors.











