law

Curie's law

Curie's law states that the magnetic susceptibility of a paramagnetic material is inversely proportional to temperature.
20 related articles · 1 formulas · 1 who worked here

Description

In 1895, while heating oxygen, palladium, and paramagnetic salts, Pierre Curie discovered a pattern: the hotter the sample, the weaker it responds to a magnetic field. The reason is the opposition between the external field, which aligns atomic magnetic moments, and thermal motion, which disorders them. At low temperatures, the field 'overpowers' the thermal chaos, but as it heats up, disorder wins, and magnetization drops. Formally, the dependence is simple: χ = C/T.

History

Pierre Curie in 1895, systematically investigating the magnetic properties of substances over a temperature range up to 1400°C, formulated this law, showing that for paramagnets, susceptibility decreases with heating, unlike diamagnets, where it is constant. In 1905, Paul Langevin provided a statistical-mechanical explanation, linking the Curie constant to the ions' magnetic moment. Subsequently, Pierre Weiss generalized the law by introducing a correction for inter-moment interaction, leading to the molecular field theory and the description of ferromagnetism.

How it works

Curie's law is used for calibrating low-temperature thermometers, determining magnetic moments of ions in crystals, and analyzing magnetic phase transitions. Boundaries of applicability: only for paramagnets with negligibly weak exchange interaction, in weak fields, and at temperatures above possible ordering. For noticeable interaction, the Curie–Weiss law is used; at very low temperatures or in strong fields, quantum models are necessary.

In practice

Based on this law, magnetic thermometers for ultra-low temperatures (below 1 K) have been developed, where traditional sensors are powerless.

Fun fact

If Curie's law worked down to absolute zero, the susceptibility would become infinite — an infinitely small field would cause infinite magnetization. In reality, at very low temperatures, quantum effects and interactions between atomic magnets come into play, smoothly transitioning to the Curie–Weiss law.

Concept graph →

Formulas

$$T(R) \propto R^{-\alpha}$$
Temperature varies with radius as a power law.
What is in the formula
Tvariabletemperature — temperature kelvin
Rvariableradius (distance from center) — radius metre
αvariablepower-law index (positive for decreasing temperature outward)
t(r)=120{k}(r/{au})^{-3/7} · 2607.02660v1

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