Curie's law states that the magnetic susceptibility of a paramagnetic material is inversely proportional to temperature.In 1895, while heating oxygen, palladium, and paramagnetic salts, Pierre Curie discovered a pattern: the hotter the sample, the weaker it responds to a magnetic field. The reason is the opposition between the external field, which aligns atomic magnetic moments, and thermal motion, which disorders them. At low temperatures, the field 'overpowers' the thermal chaos, but as it heats up, disorder wins, and magnetization drops. Formally, the dependence is simple: χ = C/T.
Pierre Curie in 1895, systematically investigating the magnetic properties of substances over a temperature range up to 1400°C, formulated this law, showing that for paramagnets, susceptibility decreases with heating, unlike diamagnets, where it is constant. In 1905, Paul Langevin provided a statistical-mechanical explanation, linking the Curie constant to the ions' magnetic moment. Subsequently, Pierre Weiss generalized the law by introducing a correction for inter-moment interaction, leading to the molecular field theory and the description of ferromagnetism.
Curie's law is used for calibrating low-temperature thermometers, determining magnetic moments of ions in crystals, and analyzing magnetic phase transitions. Boundaries of applicability: only for paramagnets with negligibly weak exchange interaction, in weak fields, and at temperatures above possible ordering. For noticeable interaction, the Curie–Weiss law is used; at very low temperatures or in strong fields, quantum models are necessary.
Based on this law, magnetic thermometers for ultra-low temperatures (below 1 K) have been developed, where traditional sensors are powerless.
If Curie's law worked down to absolute zero, the susceptibility would become infinite — an infinitely small field would cause infinite magnetization. In reality, at very low temperatures, quantum effects and interactions between atomic magnets come into play, smoothly transitioning to the Curie–Weiss law.
| T | variable | temperature — temperature kelvin |
| R | variable | radius (distance from center) — radius metre |
| α | variable | power-law index (positive for decreasing temperature outward) |











