concept

order parameter

A physical quantity that distinguishes different phases of a system, often zero in one phase and non-zero in another.
15 related articles · 2 formulas

Description

An order parameter is a physical quantity that characterizes the degree of order in a system and distinguishes different phases of matter. It is typically zero in a disordered, high-symmetry phase (like a liquid) and non-zero in an ordered, low-symmetry phase (like a crystal). The concept is central to the theory of phase transitions, where the order parameter changes continuously or discontinuously as the system transitions between phases. Examples include magnetization in ferromagnets, density difference in liquid-gas transitions, and the superconducting gap in superconductors.

History

The concept of an order parameter was formalized by Lev Landau in the 1930s as part of his theory of phase transitions, which he developed to describe second-order transitions. Landau's phenomenological approach was later extended by Vitaly Ginzburg and others to include spatial variations, leading to the Ginzburg-Landau theory of superconductivity.

How it works

The order parameter is defined so that it captures the essential symmetry breaking that occurs at a phase transition. For instance, in a ferromagnet, the order parameter is the net magnetization, which is zero above the Curie temperature (random spins) and non-zero below it (aligned spins). In a superconductor, the order parameter is a complex number representing the macroscopic wavefunction of Cooper pairs; its magnitude is zero in the normal state and non-zero in the superconducting state. The behavior of the order parameter near the critical point determines the universality class of the transition.

In practice

Order parameters are used in materials science to design and understand new materials, such as high-temperature superconductors, and in condensed matter physics to study exotic phases like topological insulators and quantum spin liquids. They also appear in soft matter physics to describe liquid crystals and polymers.

Fun fact

In the 2012 Nobel Prize-winning discovery of the Higgs boson, the Higgs field's vacuum expectation value acts as an order parameter for the electroweak symmetry breaking, giving mass to elementary particles.

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Formulas

$$\tau = -\frac{1}{2} \tanh\left(\frac{\beta}{2} D_{\tau}\right)$$
Equilibrium order parameter determined self-consistently via effective field.
What is in the formula
\tauvariableOrder parameter (e.g., magnetization) — order parameter
\betavariableInverse temperature (1/k_B T) — inverse temperature per joule
D_{\tau}variableEffective field (mean field) acting on the order parameter — effective field joule
\tanhoperatorMaps real numbers to (-1,1), typical for spin-1/2 systems — hyperbolic tangent
$$F(\psi) = a \psi^2 + b \psi^4 + c \psi^6 - f_{\text{ext}} \psi$$
Describes phase transitions with order parameter.
What is in the formula
FvariableLandau free energy density — free energy density joule per cubic metre
ψvariableorder parameter — order parameter
avariablecoefficient of quadratic term, temperature-dependent — landau coefficient a joule per cubic metre
bvariablecoefficient of quartic term — landau coefficient b joule per cubic metre
cvariablecoefficient of sixth-order term — landau coefficient c joule per cubic metre
f_extvariableexternal field coupled to the order parameter — external field joule per cubic metre

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