oxidation

Picture a tiny hole in a sheet of graphene: a single missing carbon atom. It used to be thought that a water molecule splits apart at this defect only on its own, in dry gas. But if liquid water is sloshing all around, everything changes.

A stack of pages that has been flipped through many times remembers it: some sheets lie flat, others stick up, and creases remain here and there. Layered materials behave much the same way when ions enter them.

A transparent film of bismuth tungstate sits on a substrate and does not conduct electricity. Three minutes in a cloud of nitrogen plasma, and it turns black, with resistance dropping by a factor of a billion.

A fusion reactor is like a super-hot furnace where plasma reaches millions of degrees. The walls are made of tungsten, the most refractory metal there is. But even tungsten needs protection: fast particles from the plasma bombard the surface and knock atoms loose. These ejected atoms enter the plasma and cool it down, like a spoonful of cold milk in hot tea.

Turn off the stove, and water stops boiling almost instantly. In the world of catalysis, researchers expected a similar picture: stop the reaction, and all intermediate particles vanish right away. But fresh observations of platinum nanoparticles tell a different story.

In dark interstellar clouds where new stars are born, chemistry starts with a tiny particle — the trihydrogen ion (H₃⁺). It collides with other atoms and sets off a cascade of reactions that build ever more complex molecules. For a long time, it was thought that the main reaction producing it, H₂⁺ colliding with H₂, only happens in the gas phase.

A camera flash that fires in a thousandth of a second doesn't heat the subject — unlike a regular flash that lasts a full second. A similar trick has been found in radiotherapy: when a radiation dose is delivered in milliseconds instead of minutes, healthy tissues suffer less. This is called the FLASH effect.

The mystery of the radius valley — a sharp drop in the number of exoplanets with radii ~1.8 Earth — haunts astronomers. JWST, transit surveys like Kepler and TESS draw a clear gap: rocky super-Earths and gaseous sub-Neptunes are separated by almost a chasm.

The Moon is an airless sphere of dense rocky grit called regolith. When fast particles from space slam into it, muons are born in the soil — unstable relatives of electrons, but two hundred times heavier. Most fly downward and fade away in the depths. But those that pop upward into the vacuum can travel tens of kilometers before decaying.

In the coastal shallows, where water retreats and returns, life follows the rhythm of the sun. The brownish film on the mud's surface is not just dirt but a dense community of tiny diatoms. By day they get plenty of light for photosynthesis, but when the sun gets too intense, a chemical storm brews inside the cells.

Young Earth was a boiling sphere of liquid rock, while Theia, which crashed into it, had had time to cool and solidify. It’s like dropping a chunk of cold butter into a pot of soup: the soup splashes out, but the butter barely moves. Similarly, Earth’s interior spewed into space, forming a cloud of cosmic dust and debris.

If you don’t stir a layered cocktail, the heavy syrup sinks to the bottom. A young planet is much the same — a seething ocean of molten rock. As it cools, minerals crystallize: some, like iron, get heavy and sink, while others float. You’d think a dense layer would pile up at the core.

A bridge of aluminum just a few atoms thick is the heart of many quantum devices. Current flows through such a bridge without resistance, and it can be controlled with a magnetic field. These bridges are called Josephson junctions, after the British physicist who described their behavior.

An ordinary kitchen knife made of niobium would suddenly start conducting electricity with zero loss at −258 °C. That's how superconductivity works, and you can "switch it on" right at the metal's surface by blasting it with a laser in a nitrogen atmosphere.

A memristor is a resistor with a memory: after the current is turned off, it retains its resistance. Inside, a thin film of metal oxide is sandwiched between two metal electrodes. When a strong current is first passed through the device, conductive filaments of oxygen vacancies form in the oxide, and the resistance drops sharply.

Europa's surface is an icy armor continuously bombarded by charged particles from Jupiter's magnetosphere. Electrons slam into the ice's crystal lattice, lose energy, and kick off chemical reactions. Until now, there was no tool to show how deep such bombardment pierces the ice.

Diamond is the hardest natural material, and working with it usually feels like a sculptor using a jackhammer: rough, with cracks and chips. But electronics demands jeweler-like precision, because diamond conducts heat superbly, withstands high temperatures, and can work in quantum devices.

Lunar dust looks like gray sand, but there's not a breath of air in it. Oxygen is there — tightly bound in the rocks, like sugar in caramel. To get it out, you need to break chemical bonds, and scientists are looking for the simplest way. In the lab, they took artificial lunar soil made from samples from the Apollo missions and China's Chang'e.

Vanadium oxide is a material that can act as an insulator, not conducting electricity, or as a conductor, like a metal. The switch takes trillionths of a second, and that's what makes it a candidate for ultrafast electronic devices. But exactly how it happens has long been a mystery.

On the exoplanet TRAPPIST-1, oxygenic photosynthesis, the process by which light energy is converted into chemical energy with oxygen as a byproduct, is losing the race for survival. This M-dwarf star emits mostly in the infrared, not in the visible range like the Sun.

When countless asteroids pummeled the young Earth, they tore chunks from its mantle. These fragments spiraled in a cosmic disk around the planet and, like a snowball in a blizzard, fused into the Moon.

Lunar rocks brought a puzzle: their age is 4.35 billion years, but the Moon itself should have appeared 150 million years earlier. The missing time is hidden in tidal heating. When the Moon hung closer to Earth, Earth's gravity acted like tireless hands: it constantly kneaded and bent the satellite.

After the Moon's birth, Earth resembled a sizzling lump of dough: a continuous liquid magma and a dense shroud of gases. The Moon acted like a giant spoon, constantly kneading this lump with its gravity. Friction generated heat, delaying cooling.

The Moon harbors a secret that has puzzled planetary scientists for decades: its isotopic composition is almost indistinguishable from Earth's. According to the canonical giant impact model, the Moon should have inherited most of its material from the impactor Theia, a Mars-sized planet that slammed into the young Earth.