The production of light elements like helium and lithium in the early universe, shortly after the Big Bang.Primordial nucleosynthesis, also known as Big Bang nucleosynthesis (BBN), is the production of light atomic nuclei (mostly helium-4, deuterium, helium-3, and lithium-7) during the first few minutes after the Big Bang. At that time, the universe was a hot, dense plasma of protons, neutrons, and electrons. As it expanded and cooled to about a billion degrees, protons and neutrons began to fuse, creating the first stable nuclei. This process stopped after about 20 minutes when the temperature dropped too low for further fusion.
The theory was developed in the late 1940s by George Gamow, Ralph Alpher, and Hans Bethe, with the famous 'Alpher-Bethe-Gamow' paper in 1948. The prediction of cosmic microwave background radiation was a byproduct of this work.
The process began when the universe was about one second old and the temperature was around 10 billion Kelvin. Neutrons and protons were in equilibrium via weak interactions. As the temperature dropped, the neutron-to-proton ratio froze at about 1:7. Then, deuterium (a proton-neutron pair) could form, and subsequent reactions built up helium-4, which is very stable. Almost all neutrons that survived ended up in helium-4, leaving small traces of deuterium, helium-3, and lithium-7.
Primordial nucleosynthesis provides a precise prediction for the abundance of light elements in the universe, which is used to test cosmological models and constrain the baryon density and the number of neutrino species.
The observed abundance of lithium-7 in old stars is about three times lower than predicted by BBN, a discrepancy known as the 'cosmological lithium problem' that remains unresolved.















