A nanocrystal is a crystalline particle with dimensions on the order of nanometers.A nanocrystal is a crystalline particle with dimensions on the order of nanometers — typically from 1 to 100 nanometers. At this scale, the crystal's physical properties are dominated by quantum confinement effects: electrons and holes are squeezed into a space smaller than their natural wavelength, which quantizes their energy levels. This means that the color of light emitted by a semiconductor nanocrystal (often called a quantum dot) depends on its size — smaller crystals emit bluer light, larger ones redder — even though they are made of the same material.
The concept of quantum confinement in nanocrystals was developed in the early 1980s by Alexei Ekimov and Alexander Efros (who studied glass-embedded copper chloride crystals) and independently by Louis Brus at Bell Labs, who explained the size-dependent color of colloidal cadmium sulfide particles.
In a bulk crystal, electrons occupy continuous energy bands. When the crystal shrinks to the nanometer scale, the electron wavefunction is confined in all three dimensions, and the allowed energies become discrete, like particles in a box. The energy gap between the highest occupied and lowest unoccupied states increases as the size decreases, so the crystal absorbs and emits photons of higher energy (shorter wavelength). The surface also plays a larger role, as a significant fraction of atoms reside on the surface, affecting stability and reactivity.
Nanocrystals are used in commercial display technology (QLED TVs), biological imaging as fluorescent labels, and in solar cells to enhance light absorption.
A single gram of a typical nanocrystal material contains about 10^19 individual crystals — more than the number of stars in the observable universe.














