A technique using neutron scattering to probe the magnetic structure of materials, as neutrons are sensitive to magnetic fields.Neutron diffraction is a technique used to probe the atomic and magnetic structure of materials by firing a beam of neutrons at a sample and analyzing the pattern of scattered neutrons. Because neutrons have no electric charge but possess a magnetic moment, they interact strongly with magnetic fields and can reveal the arrangement of magnetic moments in a material — something X-rays, which interact with electrons, cannot do directly. This makes neutron diffraction indispensable for studying magnetic materials, from simple ferromagnets to complex quantum magnets.
Neutron diffraction was first demonstrated in 1945 by Ernest Wollan and Clifford Shull at Oak Ridge National Laboratory. Shull later shared the 1994 Nobel Prize in Physics for his contributions to neutron scattering techniques.
A beam of neutrons with a well-defined wavelength is directed at a crystalline sample. The neutrons scatter off the atomic nuclei (nuclear scattering) and off the magnetic moments of unpaired electrons (magnetic scattering). The scattered neutrons interfere constructively at specific angles, producing a diffraction pattern of peaks. By analyzing the positions and intensities of these peaks, scientists can determine the positions of atoms and the orientation and magnitude of magnetic moments in the crystal lattice.
Neutron diffraction is used in materials science to study magnetic structures, in engineering to measure residual stresses in components, and in biology to locate hydrogen atoms in proteins, which are invisible to X-rays.
Neutrons are so penetrating that they can pass through thick metal containers, allowing scientists to study materials under extreme conditions like high pressure or temperature inside specialized furnaces and cryostats.














