substance

thorium 229

An isotope of thorium with a low-energy nuclear isomer, used in nuclear clock research.
34 related articles

Description

Thorium-229 is a radioactive isotope with a unique nuclear isomer — a metastable excited state lying only about 8.4 electronvolts above the ground state, the lowest known nuclear excitation. This energy gap is in the ultraviolet range, accessible by lasers, unlike typical nuclear transitions that require gamma rays. This makes thorium-229 the prime candidate for building a nuclear clock, a timekeeping device that ticks at the frequency of a nuclear transition, which is far more stable against environmental perturbations than atomic transitions. Such a clock could probe variations in fundamental constants, detect dark matter, and test relativity with unprecedented precision.

History

The low-energy isomer was predicted in 1976 by V.I. Zhudov and colleagues, and first observed in 1994 by a group at the University of Texas. The first direct laser excitation of the isomer was achieved in 2023 by a team at CERN, marking a milestone in nuclear clock development.

How it works

The nucleus of thorium-229 has two energy levels very close together. By exciting the nucleus with a precisely tuned ultraviolet laser, it jumps to the isomer state and then decays, emitting a photon. The frequency of this transition is extremely sharp and insensitive to magnetic fields, electric fields, and temperature, because the nucleus is well shielded by electrons. To build a clock, one traps thorium ions or embeds them in a crystal, then locks a laser to the nuclear transition frequency, counting its oscillations as 'ticks'.

In practice

Thorium-229 nuclear clocks could outperform atomic clocks in precision, enabling tests of fundamental physics, geodesy (measuring Earth's gravitational field), and potentially navigation. They are also used in research on nuclear structure and as a platform for quantum optics with nuclei.

Fun fact

The energy difference in thorium-229 is so small that it can be bridged by a single ultraviolet photon, which is why it is the only nucleus that can be manipulated with tabletop lasers rather than particle accelerators.

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