Materials designed to absorb, store, and release hydrogen efficiently for energy applications.Hydrogen storage materials are substances engineered to absorb, hold, and release hydrogen gas under controlled conditions. They are central to the vision of a hydrogen economy, where hydrogen serves as a clean fuel for vehicles, power generation, and portable electronics. The challenge is that hydrogen has very low density as a gas, and compressing or liquefying it requires significant energy and heavy tanks. These materials aim to store hydrogen at higher densities within a solid or liquid matrix, making it safer and more practical to use.
Research intensified in the 1970s during the oil crises, with early work on metal hydrides like lanthanum-nickel (LaNi5) for reversible hydrogen storage. The field expanded with the discovery of carbon nanomaterials and metal-organic frameworks in the 1990s and 2000s.
The materials work through either physisorption or chemisorption. In physisorption, hydrogen molecules are weakly bound to the surface of a porous material, like metal-organic frameworks or activated carbon, relying on van der Waals forces. In chemisorption, hydrogen atoms form chemical bonds with the material, as in metal hydrides (e.g., magnesium hydride) or complex hydrides (e.g., sodium borohydride). The release of hydrogen is triggered by heat, pressure change, or a catalyst, reversing the absorption process.
Used in fuel cell vehicles (e.g., Toyota Mirai uses a high-pressure tank, but solid-state storage is a research goal), portable power units, and stationary energy storage for renewable sources.
A single rhodium atom can act as a 'trap' for hydrogen, holding it in place like a mousetrap, as demonstrated in a 2024 study.















