nickelate superconductivity

Picture a fireplace poker shoved into a blast furnace. Ordinary steel would soften and sag within minutes. Nickel-based superalloys, which make up turbine blades in jet engines, work up to 1300 °C, but beyond that they give in too. Now look at this new niobium-based alloy: at 1500 °C it retains strength comparable to cold aluminum. The secret lies in its internal architecture.

A thin film of zirconium nitride lies on a magnesium oxide substrate. Its thickness is two-tenths of a micron, like a spider's web, but inside it quantum life is boiling. When cooled to half a kelvin, superconductivity does not disappear all at once: it breaks up into rare islands that still hold on amid the disorder.

In chemistry's storeroom, records of substances no one thought were special gathered dust. It turns out that among them hide 2D materials — thin as a sheet of paper, but strong and with unexpected properties. Scientists ran a computer search through databases, and it pulled out 38 candidates that had not been recognized as 2D before.

A tiny sandwich of oxides, grown layer by layer, becomes perfectly conducting at about minus 200 degrees Celsius. This is not a magic trick but a new chapter in the search for high-temperature superconductors.

The cosmic detective story began with a quiet flash in the optical band. AT2019wzc slowly brightened and faded like a smoldering ember. But hidden inside was something more energetic — repeating soft X-ray bursts that astronomers call quasi-periodic eruptions. These eruptions last minutes to hours and repeat every few hours or days.

A film sliver thinner than a human hair was placed between diamond anvils and squeezed. The pressure climbed — a hundred thousand atmospheres, half a million, a million… Yet the material kept conducting electricity without resistance.

Under pressure, the layered crystal La₃Ni₂O₇ behaves like an orchestra where the conductor adjusts the volume of different instrument sections. Compression increases electron hopping between layers — which, one might think, should boost superconductivity. But at the same time, some electrons become too mobile.

A ceramic plate as thin as a soap film, and through it flows current with zero resistance. That's the superconductivity achieved in nickelates, relatives of the famous cuprate superconductors. Previously, this required enormous pressure, comparable to that at the ocean floor.

Lossless current is the dream of energy technology. Some materials become superconductors, but usually only at extreme cold. Recently, in the family of nickelates, compounds based on nickel, candidates were found that work at higher temperatures.

A layered cake where each tier conducts electricity differently: that's the structure of the crystal La3Ni2O7, a compound of nickel, lanthanum, and oxygen. Current flows differently along the layers than across them.

A piece of metal is cooled to minus two hundred degrees, and electric current begins to flow through it without the slightest friction, like water in a pipe flowing without touching the walls. This behavior is called superconductivity.

The nickelate family consists of layered crystals, like a stack of pancakes: nickel and oxygen layers alternate with lanthanum spacers. Two years ago, superconductivity was discovered in them — the ability to conduct electricity without resistance when cooled.

In murky mud, between two electrodes, long chains of bacteria line up: each one as thin as a microscopic cable. Every such filament conducts current over a full centimeter, a true marathon for a microbe.

Superconductors conduct current without loss, but usually require extreme cold. Hg1223 — a mixture of mercury, barium, calcium, copper and oxygen — breaks the rule: it stops resisting current already at –139°C. The secret is that the strong electrical repulsion between electrons forces them to pair up.

A bridge made of two rows of planks bends under the feet of pedestrians, and each step gets a boost from the elastic motion of the deck. A similar principle underlies superconductivity: electrons glide without resistance because the atomic lattice itself adapts to them. In nickel-based materials, this picture has long been elusive.

A packed stadium: fans mill about chaotically, creating jostling and resistance. That's how electrons behave in an ordinary conductor. In superconductivity, they pair up and move in sync, like spectators holding hands and calmly leaving the stands, without losing energy.

The La3Ni2O7 crystal resembles a layered pie, where the filling of nickel and oxygen atoms alternates with lanthanum layers. At ambient pressure, it does not conduct without resistance, but squeeze it or grow it as a thin film, and high-temperature superconductivity emerges.

Two paper-thin sheets of a semiconductor are stacked and slightly rotated — by about three to four degrees. The atomic lattices don't match, creating a large-scale pattern — a moiré, like the ripples from two washboards shifted by a small angle. In this pattern, electrons move quite differently than in a regular crystal.

A layered cake of atomic planes of nickel and oxygen: that's how bilayer nickelates are built. Two such planes are separated by a spacer layer. If an oxygen atom sits in that spacer, it acts as a bridge: it links the layers and triggers a state in which electrons move without resistance.

A crystal is like a city: if the streets are crooked, traffic jams. In a crystal, the streets are atomic rows, and the traffic is the flow of electrons. Any tiny imperfection, impurity, or atomic displacement makes electrons scatter. Scientists from several labs have learned to grow crystals so that the "streets" are almost perfectly straight. The method is called horizontal vapor transport.

An ordinary kitchen knife made of niobium would suddenly start conducting electricity with zero loss at −258 °C. That's how superconductivity works, and you can "switch it on" right at the metal's surface by blasting it with a laser in a nitrogen atmosphere.

A superconductor is a material that, when strongly cooled, loses its electrical resistance: current flows through it without losses. Scientists took a layered crystal of PdTe2, similar to a stack of sheets of paper, and cooled it to temperatures below 1.8 kelvin (that's about -271°C).

Table salt makes food taste better in the kitchen, but in the lab it helps grow crystals just a few atoms thick. Scientists took tin selenide and, with the help of salt, grew ultra-thin flakes from it, so thin they're called two-dimensional. The salt acted as a separator: it kept the flakes from clumping together and made them lie flat on the substrate, like pancakes on a griddle.

Inside copper-based superconductors, materials that carry current without loss at unexpectedly high temperatures, there is a hidden phase. It behaves like an ordinary metal, but it's invisible in standard measurements.

Electric current in a superconductor is like a crowd running down a frictionless corridor. But in type-II superconductors there are obstacles, tiny vortices of magnetic field, that the current shoves out of place. Once a vortex moves, resistance appears and the current drops.

A superconductor is a material that, when cooled sufficiently, conducts electricity without losses, like water flowing through a perfectly smooth pipe. But if you hit it with a brief flash of light, it quickly loses this property.

A thin film of niobium and tin conducts electricity without resistance — until you make it really thin. Then it suddenly becomes an insulator. A team of physicists tested what happens when you add a bit more tin to the film than the formula calls for.

A quantum computer is like a musical instrument: even a tiny scratch on a string ruins the sound. Instead of strings, we have superconducting resonators — thin traces of titanium nitride on a silicon wafer.

The layered material (SnS)1.15(TaS2) resembles a stack of paper, where the sheets conduct electricity and the interlayers prevent them from sticking together. At ambient pressure, this material conducts current without resistance, making it a superconductor.

Weighing a piece of ice in a glass of water can tell you how much water has already frozen. If the scale is off by a factor of three, the ice will appear much larger than it really is. A similar story happened with calculations of the superconducting phase in a crystal of nickel, lanthanum, and samarium under high pressure.

A scale with a faulty calibration shows more than is actually there, and a piece of cheese seems heavier. A similar glitch occurred in measuring superconductivity in nickelates, materials that conduct electricity without resistance under certain conditions.

A metal bar made of five different metals (hafnium, niobium, scandium, titanium, and zirconium) sits in a furnace. After heating to 600 degrees, regions appear inside it that look like a pattern of two mixed metals, like marble veins.

An old T-shirt was dissolved in alkali to produce a gel, and it became the heart of an energy storage device. The second component was made from chitosan, a substance derived from shrimp shells. No metals: just recycled cotton and seafood. The gel was soaked in ammonium salt, and its conductivity nearly doubled: from 17.1 to 37.8 millisiemens per centimeter.

Metal is like a rope made of many strands: pull too hard and it snaps. Engineers have long sought a way to make it both strong and flexible at the same time. Typically, additives that increase strength make the metal brittle. But a team of materials scientists found a loophole: they added a small amount of nitrogen to the CrMnFeCoNi alloy, just one atom in a hundred, and got an unexpected result.

A superconductor is like a city where electrons stop jostling and start moving in pairs, like people strolling arm in arm. In neodymium-strontium nickelate (Nd₀.₈Sr₀.₂NiO₂), this 'parade' kicks in at around 10 kelvin (minus 263 degrees Celsius), but not uniformly.

Electrons in a metal are like a crowd in a subway: each on their own, but at the slightest push, everyone moves at once. Physicists call this collective oscillation of the electron gas a plasmon. In superconductors, these oscillations are especially important because they reveal how electrons interact with each other.

The needle tip that you drag across a surface to feel its bumps has now grown an ultrasensitive "nose" for magnetic fields. Scientists have assembled a tiny superconducting loop on the end of a cantilever (a thin, flexible beam like the one in an atomic force microscope) that catches the slightest fluctuations in magnetic flux.

At a temperature of 4.3 degrees above absolute zero, a crystal of palladium telluride stops resisting electric current. Electrons pair up and move without loss, like a crowd holding hands. But this superconductor seems to have not one but two different ways of pairing.

Measured dipole moment of tantalum-181: 3.39 × 10⁻³² e·cm — like spotting a one-atom shift across the entire Solar System. An ordinary atomic nucleus is perfectly balanced, like a spinning top. In tantalum, that balance is broken: the positive and negative charges are slightly offset from each other.