nickelate

Picture a fireplace poker shoved into a blast furnace. Ordinary steel would soften and sag within minutes. Nickel-based superalloys, which make up turbine blades in jet engines, work up to 1300 °C, but beyond that they give in too. Now look at this new niobium-based alloy: at 1500 °C it retains strength comparable to cold aluminum. The secret lies in its internal architecture.

A frozen orchestra where musicians swap seats when the conductor, magnetism, sets a new score. In a spinel crystal, iron and magnesium atoms sit in two types of seats: some surrounded by four neighbors, others by six. At room temperature, they barely stir, but cool the material to 5 K and a mass migration begins.

A tiny black hole flies through a hydrogen cloud and stretches atoms like taffy. That is what a superconductor looks like when it traps a persistent current: a material in which electricity flows without losses turns into a miniature permanent magnet.

Old treasure maps were drawn from hearsay: someone found gold by a river, someone else in the mountains, and each person dug in their own spot. High-temperature superconductors went the same way: cuprates were found in some compounds, iron pnictides in others, nickelates in yet others, and there was no common map.

In a thin layer of liquid crystal, molecules usually lie like matches in a box — aligned in one direction but randomly oriented: some point up, others down. To make all the matches point the same way, you need a special molecular architecture. Scientists have found a chemical trick that does this almost automatically.

A metal made of five different atoms is like a soup with bits of carrot, peas, potato, onion, and meat floating in it. Each bit is its own element: chromium, vanadium, titanium, niobium, and tantalum. Such an alloy is called high-entropy: there is no single order, and the atoms are mixed almost randomly.

In chemistry's storeroom, records of substances no one thought were special gathered dust. It turns out that among them hide 2D materials — thin as a sheet of paper, but strong and with unexpected properties. Scientists ran a computer search through databases, and it pulled out 38 candidates that had not been recognized as 2D before.

A tiny sandwich of oxides, grown layer by layer, becomes perfectly conducting at about minus 200 degrees Celsius. This is not a magic trick but a new chapter in the search for high-temperature superconductors.

A film sliver thinner than a human hair was placed between diamond anvils and squeezed. The pressure climbed — a hundred thousand atmospheres, half a million, a million… Yet the material kept conducting electricity without resistance.

Under pressure, the layered crystal La₃Ni₂O₇ behaves like an orchestra where the conductor adjusts the volume of different instrument sections. Compression increases electron hopping between layers — which, one might think, should boost superconductivity. But at the same time, some electrons become too mobile.

Many materials behave like finicky ice: at one pressure they melt, at another they turn harder. Superconductors in the cuprate family are no exception. Their ability to carry current without loss depends on how tightly the crystal lattice is squeezed. In a new study, physicists traced this dependence for the compound Bi-2223.

A ceramic plate as thin as a soap film, and through it flows current with zero resistance. That's the superconductivity achieved in nickelates, relatives of the famous cuprate superconductors. Previously, this required enormous pressure, comparable to that at the ocean floor.

Lossless current is the dream of energy technology. Some materials become superconductors, but usually only at extreme cold. Recently, in the family of nickelates, compounds based on nickel, candidates were found that work at higher temperatures.

In the furnace of star formation, the heat reaches 900 degrees Celsius, like a glowing blast furnace. It is in this hellish heat that cosmic crystals are born. Astronomers have for the first time caught the moment when crystalline dust appears right during an accretion flare (when the star gobbles up surrounding gas) at the very young star EC 53, still cocooned in dense gas.

A layered cake where each tier conducts electricity differently: that's the structure of the crystal La3Ni2O7, a compound of nickel, lanthanum, and oxygen. Current flows differently along the layers than across them.

A piece of metal is cooled to minus two hundred degrees, and electric current begins to flow through it without the slightest friction, like water in a pipe flowing without touching the walls. This behavior is called superconductivity.

The nickelate family consists of layered crystals, like a stack of pancakes: nickel and oxygen layers alternate with lanthanum spacers. Two years ago, superconductivity was discovered in them — the ability to conduct electricity without resistance when cooled.

Hundreds of light-years away, there's a planet that looks like a giant mirror. LTT9779b reflects most of the light that hits it — far more than you'd expect from a Neptune-sized body. Astronomers have long debated what makes it so shiny: a thick carbon-rich haze or a layer of clouds. The James Webb Space Telescope has helped settle the debate.

Engineers create an alloy for solar concentrators by adding hard particles — like raisins in dough, to help it hold its shape under extreme heat. Too big a raisin and the material cracks. Previously, scientists manually counted these particles on microscope images.

Usually, superconductivity is a story about cold. The lower the temperature, the easier it is for electrons to pair up and flow without resistance. But in a new study, physicists grew thin films of nickelates doped with europium and saw the opposite picture.

In murky mud, between two electrodes, long chains of bacteria line up: each one as thin as a microscopic cable. Every such filament conducts current over a full centimeter, a true marathon for a microbe.

Using laser spectroscopy — a method akin to listening to the echo from a crystal — physicists examined the layered material. They found regions where electrons move freely (Fermi pockets) and noticed that each such region behaves in its own way.

Superconductors conduct current without loss, but usually require extreme cold. Hg1223 — a mixture of mercury, barium, calcium, copper and oxygen — breaks the rule: it stops resisting current already at –139°C. The secret is that the strong electrical repulsion between electrons forces them to pair up.

Electrons in a conductor are like a chaotic crowd: colliding, they lose energy, and resistance arises. In a superconductor, however, they move in unison, like partners in a well-coordinated dance, without touching each other. This state has reduced энтропией — meaning disorder. Such behavior is rare for gold and copper.

Imagine a sandwich where the bread is made of copper oxide layers and the filling is a thin layer of strontium ions. That's the infinite-layer cuprate, the simplest version of superconducting ceramics, conceived nearly 40 years ago.

A bridge made of two rows of planks bends under the feet of pedestrians, and each step gets a boost from the elastic motion of the deck. A similar principle underlies superconductivity: electrons glide without resistance because the atomic lattice itself adapts to them. In nickel-based materials, this picture has long been elusive.

A packed stadium: fans mill about chaotically, creating jostling and resistance. That's how electrons behave in an ordinary conductor. In superconductivity, they pair up and move in sync, like spectators holding hands and calmly leaving the stands, without losing energy.

The dance floor is full of couples waltzing. Usually, partners move in opposite directions: one steps forward, the other backward, to keep the overall rhythm.

The La3Ni2O7 crystal resembles a layered pie, where the filling of nickel and oxygen atoms alternates with lanthanum layers. At ambient pressure, it does not conduct without resistance, but squeeze it or grow it as a thin film, and high-temperature superconductivity emerges.

A layered cake of atomic planes of nickel and oxygen: that's how bilayer nickelates are built. Two such planes are separated by a spacer layer. If an oxygen atom sits in that spacer, it acts as a bridge: it links the layers and triggers a state in which electrons move without resistance.

In familiar metals like copper, electrons move almost independently, like cars on an open highway. Resistance arises from rare collisions and can be described by simple formulas.

A crystal is like a city: if the streets are crooked, traffic jams. In a crystal, the streets are atomic rows, and the traffic is the flow of electrons. Any tiny imperfection, impurity, or atomic displacement makes electrons scatter. Scientists from several labs have learned to grow crystals so that the "streets" are almost perfectly straight. The method is called horizontal vapor transport.

An ordinary kitchen knife made of niobium would suddenly start conducting electricity with zero loss at −258 °C. That's how superconductivity works, and you can "switch it on" right at the metal's surface by blasting it with a laser in a nitrogen atmosphere.

Nitrogen, the very gas we breathe, behaves like a finicky metal under a million atmospheres of pressure. In a diamond anvil cell, it is squeezed to 78–98 gigapascals and heated with a laser to 1800–2500 kelvin. Under these conditions, N₂ molecules rearrange into crystals that can store energy more densely than explosives.

A superconductor is a material that, when strongly cooled, loses its electrical resistance: current flows through it without losses. Scientists took a layered crystal of PdTe2, similar to a stack of sheets of paper, and cooled it to temperatures below 1.8 kelvin (that's about -271°C).

Table salt makes food taste better in the kitchen, but in the lab it helps grow crystals just a few atoms thick. Scientists took tin selenide and, with the help of salt, grew ultra-thin flakes from it, so thin they're called two-dimensional. The salt acted as a separator: it kept the flakes from clumping together and made them lie flat on the substrate, like pancakes on a griddle.

Inside copper-based superconductors, materials that carry current without loss at unexpectedly high temperatures, there is a hidden phase. It behaves like an ordinary metal, but it's invisible in standard measurements.

A copper crystal is squeezed in diamond anvil cells. As pressure mounts, a battle unfolds inside the material between two states: one prepares electrons for superconductivity, the other hinders their pairing. Scientists tracked this struggle using ultrashort laser pulses.

An alloy of palladium and tellurium with a small amount of gold added behaves like a wire that loses its resistance when cooled. At ambient pressure, the three samples with different gold contents had superconducting transition temperatures of 2.7, 4.1, and 4.6 kelvin — colder than a freezer, roughly like deep space.

A woven basket made of willow twigs holds its shape thanks to the interweaving. A similar pattern, triangles linked into a flat network, has been found in a new crystal with the formula Cs₃V₉Te₁₃. Here, vanadium atoms form two sets of triangles that pierce each other like threads in fabric. This pattern is not just pretty: it forces electrons to move along special "flat" energy pathways.