A gas composed of two hydrogen atoms bound together, common in cool stellar atmospheres.Molecular hydrogen (H₂) is the simplest and most abundant molecule in the universe. It consists of two hydrogen atoms bound by a covalent bond. Unlike atomic hydrogen, which emits radio waves at 21 cm, H₂ has no permanent dipole moment, making it nearly invisible to direct radio observations. Instead, astronomers detect it indirectly through its effects on dust, through tracer molecules like carbon monoxide (CO), or through its ultraviolet absorption in the Lyman and Werner bands. Molecular hydrogen is the primary fuel for star formation: dense clouds of H₂ collapse under gravity to form stars, and the gas is also a key component of the interstellar medium.
Molecular hydrogen was first detected in space in 1970 by George Carruthers using a rocket-borne ultraviolet spectrometer, which observed absorption in the direction of the star ξ Persei. The theoretical prediction of its abundance in interstellar clouds dates back to the 1960s.
H₂ forms on the surfaces of dust grains in the interstellar medium, where two hydrogen atoms meet and combine. The molecule is fragile and can be dissociated by ultraviolet radiation, so it survives mainly in cold, dense clouds that shield it from starlight. In these clouds, H₂ acts as a coolant, radiating away heat through rotational and vibrational transitions, allowing the gas to cool and collapse further. The presence of H₂ is often inferred from observations of CO, which is excited by collisions with H₂ and emits readily detectable millimeter-wave radiation.
Understanding H₂ is crucial for modeling star formation, the evolution of galaxies, and the chemistry of the early universe. It also informs studies of exoplanet atmospheres, where H₂ is a major constituent of gas giants.
Although H₂ is the most abundant molecule in the universe, it is notoriously difficult to detect directly, which is why astronomers often call it 'the invisible molecule' and rely on proxies like CO.











