quantity

polarizability

The ability of an atom's electron cloud to deform in response to an electric field.
29 related articles

Description

Polarizability is a measure of how easily an atom's or molecule's electron cloud is distorted by an external electric field. When an electric field is applied, the negatively charged electrons shift slightly relative to the positively charged nucleus, creating an induced dipole moment. This property influences how atoms interact with light, other atoms, and surfaces.

History

The concept dates back to the 19th century with the work of Faraday and Maxwell on dielectrics. The quantum mechanical treatment was developed in the early 20th century, with contributions from Schrödinger and others.

How it works

The induced dipole moment is proportional to the applied electric field, with the proportionality constant being the polarizability. In quantum mechanics, polarizability arises from the second-order perturbation of the energy levels by the electric field. It depends on the atomic structure: larger atoms with loosely bound electrons have higher polarizability. The dynamic polarizability varies with the frequency of the applied field, leading to effects like the AC Stark shift.

In practice

Polarizability is crucial in optical tweezers, where focused laser beams trap and manipulate microscopic particles, and in atomic clocks, where it determines the sensitivity to stray electric fields.

Fun fact

The polarizability of a single atom can be measured with such precision that it serves as a test of quantum electrodynamics, one of the most accurate theories in physics.

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Related articles · 29

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