
A technique measuring the difference in absorption of left and right circularly polarized X-rays by a material in a magnetic field, revealing its magnetic properties.X-ray magnetic circular dichroism (XMCD) is a spectroscopic technique that measures the difference in absorption of left- and right-circularly-polarized X-rays by a material placed in a magnetic field. This difference arises because the X-rays interact with the magnetic moments of electrons in the material, and the absorption depends on the relative orientation of the photon's angular momentum and the electron's spin. By analyzing the XMCD signal, researchers can determine the magnetic properties of a material, such as the size and direction of its magnetic moments, with element specificity — meaning they can probe the magnetism of individual chemical elements in a compound. This makes XMCD a powerful tool for studying magnetic thin films, nanoparticles, and complex oxides.
XMCD was first predicted theoretically in 1975 by Erskine and Stern, and experimentally demonstrated in 1987 by Gisela Schütz and colleagues at the German synchrotron DESY. It has since become a standard tool at synchrotron facilities worldwide.
The technique relies on the fact that circularly polarized X-rays carry angular momentum. When such X-rays hit a magnetic material, the absorption probability depends on whether the photon's angular momentum is aligned or anti-aligned with the magnetization. By measuring the absorption spectra for both polarizations and taking the difference, the magnetic contribution is isolated. The effect is strongest at absorption edges, such as the L-edges of transition metals, where the X-rays excite core electrons into unoccupied states. The magnitude of the XMCD signal is proportional to the magnetic moment, and by applying the sum rules, one can extract separate values for the spin and orbital contributions to the magnetization.
XMCD is used to characterize magnetic storage media, spintronic devices, and magnetic nanoparticles for biomedical applications, as well as to study fundamental magnetic phenomena in condensed matter physics.
XMCD can distinguish between the spin and orbital contributions to magnetism, which is crucial for designing materials for magnetic data storage, where the orbital moment often determines the stability of the magnetization.













