
A superconducting state where electron pairs carry a nonzero total momentum, forming a spatially modulated condensate.In a conventional superconductor, electrons form pairs that all move together with zero total momentum, creating a uniform quantum condensate that conducts electricity without resistance. A pair density wave (PDW) is a more exotic superconducting state where these electron pairs carry a nonzero total momentum, meaning the condensate itself is spatially modulated — its density varies periodically like a standing wave. This modulation is a form of quantum order that breaks translational symmetry, something not seen in standard superconductors.
The concept was theoretically proposed in the 1960s by Fulde and Ferrell, and independently by Larkin and Ovchinnikov, for superconductors in strong magnetic fields. The idea was later extended to zero-field cases in high-temperature superconductors, but direct experimental evidence remained elusive for decades.
The key mechanism is that electron pairs condense into a state with a finite center-of-mass momentum, rather than zero. This happens when the electronic interactions favor pairing at a nonzero wavevector, often due to competing magnetic or charge orders. The result is a superconducting order parameter that oscillates in space, creating a periodic pattern of superconducting and normal regions. This modulation can coexist with other orders, such as charge density waves, and can lead to unusual phenomena like vortices that carry fractional flux.
PDW states are studied in the context of high-temperature superconductors and ultracold atomic gases, where they may help explain the pseudogap phase and other anomalous properties. They are also relevant for designing superconducting devices with spatially varying properties.
In a PDW, the superconducting condensate can have a density that varies with a period much larger than the atomic spacing, creating a sort of 'supersolid' for electron pairs.


















