The operator representing the total energy of a quantum system, governing its time evolution.The Hamiltonian is an operator in quantum mechanics that represents the total energy of a system. It plays a central role in the Schrödinger equation, which describes how the quantum state of a system evolves over time. The Hamiltonian encodes all the information about the system's kinetic energy and potential interactions, making it the fundamental 'engine' that drives quantum dynamics.
The concept was introduced by William Rowan Hamilton in the 1830s as a reformulation of classical mechanics. It was later adapted into quantum mechanics by Erwin Schrödinger in 1925-1926, who used it to formulate his famous wave equation.
In quantum mechanics, the Hamiltonian is a mathematical operator that acts on the wavefunction. Its eigenvalues correspond to the possible energy levels of the system, and its eigenvectors are the stationary states. The time evolution of any quantum state is governed by the exponential of the Hamiltonian, which effectively 'rotates' the state in time according to its energy content.
The Hamiltonian is used in virtually all quantum physics calculations, from modeling atoms and molecules to designing quantum computers and simulating condensed matter systems.
In quantum computing, the Hamiltonian of a system can be engineered to solve optimization problems, a technique known as quantum annealing.
| ρ | variable | density matrix of the open quantum system — density matrix |
| t | variable | time — time second |
| H | variable | Hamiltonian of the system — hamiltonian joule |
| L_n | variable | Lindblad operators (jump operators) for each dissipation channel — lindblad operator |
| i | constant | imaginary unit, square root of -1 — imaginary unit = 1 |
| ħ | constant | Planck constant divided by 2π — reduced planck constant = 1.054571817e-34 joule second |
| d/dt | operator | derivative with respect to time — time derivative |
| [H, ρ] | operator | commutator of H and ρ — commutator |
| {L_n† L_n, ρ} | operator | anticommutator of L_n† L_n and ρ — anticommutator |
| ∑_n | operator | sum over all dissipation channels — sum over channels |
| H | variable | Hamiltonian operator — hamiltonian joule |
| t | variable | hopping amplitude — energy joule |
| γ_{2j} | variable | Majorana operator at site 2j — majorana operator |
| γ_{2j+1} | variable | Majorana operator at site 2j+1 — majorana operator |
| ∑ | operator | sum over lattice sites j — summation |
| H | variable | Hamiltonian (total energy operator) — hamiltonian joule |
| J | variable | Exchange coupling constant between neighboring spins — exchange coupling joule |
| \mathbf{S}_i | variable | Spin operator at site i — spin operator |
| \mathbf{S}_j | variable | Spin operator at site j — spin operator |
| \sum_{\langle i,j \r | operator | Summation over all pairs of adjacent lattice sites — sum over nearest neighbors |
| H | variable | Hamiltonian (total energy operator) — hamiltonian joule |
| J_{ij} | variable | Exchange coupling constant between sites i and j — exchange coupling joule |
| \mathbf{S}_i | variable | Spin operator at site i — spin operator |
| \mathbf{S}_j | variable | Spin operator at site j — spin operator |
| \sum_{\langle i,j \r | operator | Summation over all pairs of adjacent lattice sites — sum over nearest neighbors |
| H_eff | variable | effective static Hamiltonian — hamiltonian joule |
| H_0 | variable | time-averaged Hamiltonian — hamiltonian joule |
| H_{-1} | variable | first negative Fourier component of the Hamiltonian — hamiltonian joule |
| H_{+1} | variable | first positive Fourier component of the Hamiltonian — hamiltonian joule |
| frequency | variable | driving frequency — angular frequency radian per second |
| [ , ] | operator | measures the non-commutativity of two operators — commutator |
| E_n | variable | Perturbed energy of state n — energy joule |
| E_n^{(0)} | variable | Unperturbed energy of state n — energy joule |
| E_m^{(0)} | variable | Unperturbed energy of state m — energy joule |
| H' | variable | Perturbation Hamiltonian — hamiltonian joule |
| |n^{(0)}\rangle | variable | Unperturbed state n — quantum state |
| |m^{(0)}\rangle | variable | Unperturbed state m — quantum state |
| \sum_{m \neq n} | operator | Sum over all states m except n — summation |
| \langle m^{(0)} | H' | operator | Matrix element of perturbation between unperturbed states — matrix element |



















