equation

hamiltonian

The operator representing the total energy of a quantum system, governing its time evolution.
51 related articles · 6 formulas

Description

The Hamiltonian is an operator in quantum mechanics that represents the total energy of a system. It plays a central role in the Schrödinger equation, which describes how the quantum state of a system evolves over time. The Hamiltonian encodes all the information about the system's kinetic energy and potential interactions, making it the fundamental 'engine' that drives quantum dynamics.

History

The concept was introduced by William Rowan Hamilton in the 1830s as a reformulation of classical mechanics. It was later adapted into quantum mechanics by Erwin Schrödinger in 1925-1926, who used it to formulate his famous wave equation.

How it works

In quantum mechanics, the Hamiltonian is a mathematical operator that acts on the wavefunction. Its eigenvalues correspond to the possible energy levels of the system, and its eigenvectors are the stationary states. The time evolution of any quantum state is governed by the exponential of the Hamiltonian, which effectively 'rotates' the state in time according to its energy content.

In practice

The Hamiltonian is used in virtually all quantum physics calculations, from modeling atoms and molecules to designing quantum computers and simulating condensed matter systems.

Fun fact

In quantum computing, the Hamiltonian of a system can be engineered to solve optimization problems, a technique known as quantum annealing.

Concept graph →

Formulas

$$\frac{d\rho}{dt} = -\frac{i}{\hbar}[H,\rho] + \sum_n \left( L_n \rho L_n^\dagger - \frac{1}{2} \{ L_n^\dagger L_n, \rho \} \right)$$
Describes open quantum system evolution with dissipation.
What is in the formula
ρvariabledensity matrix of the open quantum system — density matrix
tvariabletime — time second
HvariableHamiltonian of the system — hamiltonian joule
L_nvariableLindblad operators (jump operators) for each dissipation channel — lindblad operator
iconstantimaginary unit, square root of -1 — imaginary unit = 1
ħconstantPlanck constant divided by 2π — reduced planck constant = 1.054571817e-34 joule second
d/dtoperatorderivative with respect to time — time derivative
[H, ρ]operatorcommutator of H and ρ — commutator
{L_n† L_n, ρ}operatoranticommutator of L_n† L_n and ρ — anticommutator
∑_noperatorsum over all dissipation channels — sum over channels
$$H = -it \sum_j \gamma_{2j} \gamma_{2j+1}$$
Hamiltonian for a Kitaev chain with Majorana fermion pairing.
What is in the formula
HvariableHamiltonian operator — hamiltonian joule
tvariablehopping amplitude — energy joule
γ_{2j}variableMajorana operator at site 2j — majorana operator
γ_{2j+1}variableMajorana operator at site 2j+1 — majorana operator
∑operatorsum over lattice sites j — summation
$$H = -J \sum_{\langle i,j \rangle} \mathbf{S}_i \cdot \mathbf{S}_j$$
Describes magnetic interactions between neighboring spins.
What is in the formula
HvariableHamiltonian (total energy operator) — hamiltonian joule
JvariableExchange coupling constant between neighboring spins — exchange coupling joule
\mathbf{S}_ivariableSpin operator at site i — spin operator
\mathbf{S}_jvariableSpin operator at site j — spin operator
\sum_{\langle i,j \roperatorSummation over all pairs of adjacent lattice sites — sum over nearest neighbors
$$H = -\sum_{\langle i,j \rangle} J_{ij} \mathbf{S}_i \cdot \mathbf{S}_j$$
Describes the energy of interacting spins with exchange coupling.
What is in the formula
HvariableHamiltonian (total energy operator) — hamiltonian joule
J_{ij}variableExchange coupling constant between sites i and j — exchange coupling joule
\mathbf{S}_ivariableSpin operator at site i — spin operator
\mathbf{S}_jvariableSpin operator at site j — spin operator
\sum_{\langle i,j \roperatorSummation over all pairs of adjacent lattice sites — sum over nearest neighbors
$$H_{ ext{eff}} = H_0 + rac{[H_{-1}, H_{+1}]}{ ext{frequency}}$$
Approximates the static Hamiltonian under high-frequency driving.
What is in the formula
H_effvariableeffective static Hamiltonian — hamiltonian joule
H_0variabletime-averaged Hamiltonian — hamiltonian joule
H_{-1}variablefirst negative Fourier component of the Hamiltonian — hamiltonian joule
H_{+1}variablefirst positive Fourier component of the Hamiltonian — hamiltonian joule
frequencyvariabledriving frequency — angular frequency radian per second
[ , ]operatormeasures the non-commutativity of two operators — commutator
$$E_n \approx E_n^{(0)} + \sum_{m \neq n} \frac{|\langle m^{(0)} | H' | n^{(0)} \rangle|^2}{E_n^{(0)} - E_m^{(0)}}$$
Energy correction from summing over matrix elements divided by energy differences.
What is in the formula
E_nvariablePerturbed energy of state n — energy joule
E_n^{(0)}variableUnperturbed energy of state n — energy joule
E_m^{(0)}variableUnperturbed energy of state m — energy joule
H'variablePerturbation Hamiltonian — hamiltonian joule
|n^{(0)}\ranglevariableUnperturbed state n — quantum state
|m^{(0)}\ranglevariableUnperturbed state m — quantum state
\sum_{m \neq n}operatorSum over all states m except n — summation
\langle m^{(0)} | H'operatorMatrix element of perturbation between unperturbed states — matrix element

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