
A material with electronic properties between a metal and a semiconductor, often showing high electron mobility.A semimetal is a material whose electronic band structure features a small overlap between the valence and conduction bands, resulting in a low but nonzero density of charge carriers at absolute zero. Unlike metals, which have a large Fermi surface, semimetals have very few free electrons and holes, but these carriers often exhibit extremely high mobility—meaning they can travel long distances without scattering. Examples include bismuth, graphite, and topological semimetals like tungsten diselenide (WSe₂), which have recently become a focus of condensed matter physics.
The term 'semimetal' was coined in the early 20th century to describe elements like bismuth and antimony, whose conductivity is intermediate between metals and semiconductors. The modern understanding of semimetals as topological materials emerged in the 2000s, with the prediction and discovery of Weyl and Dirac semimetals around 2015.
In a semimetal, the valence band maximum sits slightly above the conduction band minimum in energy, so electrons can spontaneously populate the conduction band even at zero temperature. The resulting carriers are few but move rapidly, especially in materials with linear energy-momentum dispersion (like graphene or Weyl semimetals), where they behave as relativistic Dirac fermions. This leads to unusual transport properties, such as large magnetoresistance and quantum oscillations.
Semimetals are used in thermoelectric devices, as components in electronic sensors, and as platforms for studying quantum phenomena; topological semimetals are being explored for next-generation transistors and spintronic devices.
Bismuth, a classic semimetal, expands by about 3.3% when it solidifies, which is why it is used in alloys for casting that need to fill intricate molds precisely.



















