concept

triplet state

A quantum state of two electrons with aligned spins, resulting in a total spin of one.
40 related articles

Description

A triplet state is a quantum state of a system with two unpaired electrons whose spins are aligned (both 'up' or both 'down'), resulting in a total spin quantum number S = 1. This gives three possible spin projections (m_s = -1, 0, +1), hence the name 'triplet'. It contrasts with the singlet state, where the spins are antiparallel (S = 0). Triplet states play a crucial role in molecular physics, photochemistry, and quantum information science.

History

The concept of triplet states was developed in the early 20th century with the advent of quantum mechanics. Friedrich Hund and Robert Mulliken contributed to understanding molecular electronic states, and the term 'triplet' was formalized in the 1920s.

How it works

In a triplet state, the two electrons occupy different spatial orbitals, and their spins are parallel. This alignment reduces electron-electron repulsion due to the Pauli exclusion principle, often making triplet states slightly lower in energy than corresponding singlet states in certain molecules. Transitions between singlet and triplet states are 'forbidden' by quantum selection rules, making triplet states long-lived (metastable). This property is exploited in technologies like organic light-emitting diodes (OLEDs) and in quantum sensing.

In practice

Triplet states are central to phosphorescent materials, OLED displays, and nitrogen-vacancy centers in diamond, which are used as quantum sensors and qubits for quantum computing.

Fun fact

In the nitrogen-vacancy center in diamond, the triplet state's spin can be manipulated with microwave pulses and read out with laser light, making it a leading platform for room-temperature quantum technologies.

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Related articles · 40

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Quantum Waves in the Macroworld: A Hair-Thin Wire
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Quantum Physics2026-08-021 minarXiv:2608.01011express
Seven Qubits Tie the Perfect Knot
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A Magnetic Staircase of Crystals
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Nuclear Experiment2026-07-101 minarXiv:2607.09551express
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Quantum Physics2026-07-091 minarXiv:2607.08634express
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At the heart of a future quantum computer might lie a tiny organic molecule shaped like a triangle. It has two 'extra' electrons that don't pair up. Such molecules are called diradicals, and their electrons can store information in a special, quantum way.
Materials2026-07-042 minarXiv:2607.03706express
Triplet Pairs: A Quantum Dance Without Steps
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Quantum Physics2026-06-301 minarXiv:2606.31726express
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HEP Phenomenology2026-06-121 minarXiv:2606.14454express
Neutrinos Entangle in Threes
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HEP Phenomenology2026-06-091 minarXiv:2606.11296express
Triple Quantum Entanglement: The Whole Is Greater Than the Sum of the Pairs
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Quantum Physics2026-06-041 minarXiv:2606.06653express
The Quantum Mpemba Paradox: Asymmetry Accelerates Order
Hot water sometimes freezes before cold: this is the Mpemba effect. In the quantum realm, a similar paradox appears: the more the equilibrium is disrupted, the faster it recovers. It's like fleeing from disorder (entropy) in reverse: the system rushes toward order, and a large initial imbalance only helps.
Strongly Correlated2026-05-261 minarXiv:2605.27484express
How magnets change the nature of a quantum transition
A long chain of atoms, each a tiny magnet. They talk to each other and to a common field, like musicians in an orchestra who hear both the conductor and their neighbors. When the external field changes, the orchestra either plays out of sync or all instruments come in together: that's a quantum phase transition.
Superconductivity2026-05-232 minarXiv:2605.24439express
Vacuum Turns an Ordinary Superconductor into an Extraordinary One
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Two black holes smash head-on at full speed — while a third one circles nearby. In ordinary life, such a crash would produce a burst of gravitational waves (ripples in space, like the ripples from a stone thrown into a pond). But here, part of the ripple passes by the massive neighbor, and changes, like light in a funhouse mirror.
Quantum Physics2026-05-152 minarXiv:2605.15945express
Schrödinger's Cat Made of Thousands of Atoms
An orchestra where every musician plays their own part, yet together they weave a complex melody: that's what a cloud of atoms looks like when their spins (intrinsic rotations, like tiny tops) oscillate in sync. Usually, these tops behave independently.
Quantum Physics2026-05-142 minarXiv:2605.14515express
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Two entangled photons fly apart in opposite directions but continue to behave as a single whole: measuring one instantly determines the state of the other. That's quantum entanglement. But sometimes it resembles a seasoned spy — leaving no traces detectable by ordinary checks.
Quantum Physics2026-05-111 minarXiv:2605.10077express
Lone Molecule Bridges Spin and Light
Quantum networks need a mediator between storage — spin — and carrier — light. No single molecule had ever pulled off such a feat. But now physicists have found a solution. They placed a carbene molecule into a crystal and cooled it to -269°C.
Biological Physics2026-05-081 minarXiv:2605.08307express
Bacterial Quantum Secret of Safe Light Harvesting
Under sunlight, molecules inside bacteria, like the beaters of a kitchen mixer, capture energy and spin electrons in the right direction. But sometimes the spin gets disrupted — 'stuck' triplet particles appear. It's as if the beater momentarily froze and then jerked backward, splashing hot liquid and scalding the walls.
Mesoscale2026-05-042 minarXiv:2605.03026express
How to Paint a Magnet with Light
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In the silence of the cosmos, the fabric of spacetime trembles almost imperceptibly: this is the quantum whisper at the scale of 10⁻³⁵ m, which until now was considered fundamentally undetectable. But collisions of black holes can turn it into a deafening scream.
Mesoscale2026-03-312 minarXiv:2604.00232express
Silicon Twin Dots: How Atoms Turn into Molecules
Two quantum dots are like two tiny pockets in a piece of silicon where an electron can sit, like a ball in a cup. When the pockets are far apart, each electron lives on its own, and its energy resembles the levels of a solitary atom.
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Quantum Channels Reveal Topology of Mixed States
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Strongly Correlated2026-03-252 minarXiv:2603.24453express
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Mesoscale2026-03-191 minarXiv:2603.18726express
Invisible Quantum Dot Stops Current
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Mesoscale2026-03-182 minarXiv:2603.17854express
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A ring of magnetic atoms resembles a round dance where each participant holds hands with their neighbors. In ordinary magnets, each atom has its own permanent magnetic moment, and they interact like little arrows striving to align opposite to each other.
HEP Experiment2026-03-161 minarXiv:2603.14878express
The Quantum Dance of Protons in Water
A drop of water on the table looks calm, but inside it, quantum life is bustling. Protons in hydrogen atoms are like tiny spinning tops that constantly rotate. Each has its own direction of spin.
Strongly Correlated2026-03-151 minarXiv:2603.14545express
Magnetic swings: why order never comes
Magnetic atoms in a solid are like compass needles: usually, when cooled, they align in one direction: that's how magnetism arises. But in TbInO3, the terbium needles sit on a triangular lattice where it's impossible to please all neighbors at once. One needle wants to point north, another south, and in the end none can settle into a stable position.
Mesoscale2026-03-081 minarXiv:2603.07806express
A Qubit for Two: Reading Two Bits in One Go
A quantum computer based on electron spins is like a row of tiny spinning tops. Each top spins either clockwise or counterclockwise: that's a qubit. To find out the result of a computation, you typically stop the top and see which way it fell. But if you have many tops, each one needs its own "eye"—an extra helper qubit.
Quantum Physics2026-03-031 minarXiv:2603.02507express
A Tiny Diamond Caught a Quantum Signal and Twisted
A tiny diamond hangs in the air, held by an electric field like a speck of dust in a beam of light. Hidden inside are defects — places where a carbon atom is replaced by nitrogen, with a vacancy nearby. These defects behave like little magnets that can be flipped with laser and microwaves.
Quantum Physics2026-02-282 minarXiv:2603.00463express
Quantum Choir of Atoms
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Mesoscale2026-01-301 minarXiv:2601.23267express
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Strongly Correlated2026-01-241 minarXiv:2601.17455express
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Chemical Physics2026-01-122 minarXiv:2601.07614express
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Quantum Physics2011-10-132 minarXiv:1110.2978express
Quantum Memory in Diamond
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