The electrode in a battery where reduction occurs and cations are reduced during discharge.The cathode is the electrode in a battery where reduction occurs during discharge — that is, where cations (positively charged ions) gain electrons. In a discharging battery, the cathode is the positive terminal; when you recharge a rechargeable battery, the roles reverse and the same electrode becomes the anode. The cathode's material determines much of a battery's voltage, energy density, and lifespan, making it a central focus of battery research.
The term 'cathode' was coined by Michael Faraday in the 1830s during his work on electrolysis, where he defined it as the electrode through which current leaves the electrolyte.
During discharge, oxidation happens at the anode, releasing electrons that travel through an external circuit to the cathode. At the cathode, cations from the electrolyte accept these electrons and are reduced, often incorporating into the cathode's crystal structure. The cathode material must be able to reversibly store and release these ions — for example, lithium ions in lithium-ion batteries — without degrading. Its stability against side reactions and structural fatigue directly affects how many charge-discharge cycles a battery can survive.
Cathode materials are the key differentiator in commercial batteries — from lithium cobalt oxide in smartphones to nickel-manganese-cobalt in electric vehicles — and are the main target of research for improving energy density and cycle life.
In a battery, the cathode is often the heaviest and most expensive component, which is why many battery innovations focus on making cathodes from cheaper and more abundant elements like iron or sulfur.
















