quantity

transition temperature

The temperature below which a material becomes superconducting.
81 related articles

Description

Transition temperature (Tc) is the critical temperature below which a material loses all electrical resistance and becomes superconducting. This is not a gradual change but a sharp phase transition: above Tc the material behaves as a normal conductor, below it electrons form Cooper pairs and condense into a macroscopic quantum state. The value of Tc is a fundamental property of each superconductor, ranging from fractions of a kelvin in some metals to over 130 K in high-temperature cuprates.

History

Heike Kamerlingh Onnes discovered superconductivity in mercury in 1911, observing zero resistance at 4.2 K. The theoretical explanation for conventional superconductors came in 1957 with the BCS theory by Bardeen, Cooper, and Schrieffer.

How it works

Below Tc, electrons with opposite momenta and spins bind into Cooper pairs via lattice vibrations (phonons) in conventional superconductors, or via other mechanisms in unconventional ones. These pairs condense into a single quantum state described by a single wavefunction, allowing current to flow without scattering. The transition is marked by the opening of an energy gap in the electronic spectrum, which can be measured directly. In some materials, the gap structure is complex (e.g., two gaps), and the transition temperature is highly sensitive to lattice strain, disorder, and dimensionality.

In practice

Superconductors are used in MRI magnets, particle accelerators, and quantum computing circuits; raising Tc is a major goal for lossless power transmission and more efficient technologies.

Fun fact

In some iron-based superconductors, a tiny amount of impurity that kills superconductivity can actually raise the transition temperature when placed in a specific position in the crystal lattice.

Concept graph →

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