A layered transition-metal dichalcogenide material that exhibits low friction when sliding against graphite.Molybdenum disulfide (MoS₂) is a layered compound belonging to the family of transition-metal dichalcogenides. It consists of sheets of molybdenum atoms sandwiched between two layers of sulfur atoms, held together by weak van der Waals forces. This structure gives it remarkable lubricating properties: when sliding against graphite or other materials, it exhibits extremely low friction, often approaching superlubricity—a state where friction nearly vanishes. Beyond lubrication, MoS₂ is a semiconductor with a band gap that becomes direct when thinned to a single layer, making it a star material in nanoelectronics and optoelectronics.
Molybdenum disulfide has been used as a lubricant since the 1960s, but its potential in electronics was recognized only in the 2010s, when researchers discovered that a single layer of MoS₂ emits light efficiently, sparking intense research into two-dimensional semiconductors.
The low friction arises because the layers are held together by weak forces, so they can slide easily over each other. When MoS₂ slides against graphite, the two materials' atomic lattices can align in a way that creates a nearly flat potential energy landscape—the atoms 'ride' over each other without locking into place, a phenomenon called structural superlubricity. This occurs when the contact is incommensurate (the lattice periods don't match), so the net lateral force averages to zero. In electronics, its semiconducting properties emerge from the d-orbitals of molybdenum, which give it a band gap that can be tuned by layer thickness.
MoS₂ is used as a dry lubricant in aerospace and automotive applications, and as a channel material in flexible transistors, photodetectors, and gas sensors.
When MoS₂ is exfoliated to a single layer, it becomes a direct-band-gap semiconductor, emitting light much more efficiently than its bulk form, which is an indirect-gap material.





















