A quantum mechanical transition between energy levels that occurs when the system changes rapidly compared to its internal timescale.A nonadiabatic transition is a quantum mechanical process in which a system moves between energy levels when an external parameter changes rapidly compared to the system's natural timescale. In contrast to adiabatic transitions, where the system slowly follows a changing Hamiltonian and remains in the same instantaneous eigenstate, nonadiabatic transitions involve sudden changes that cause the system to jump to a different energy level. These transitions are fundamental to understanding how quantum systems respond to fast perturbations and are key to phenomena like Landau-Zener tunneling and avoided crossings.
The theoretical framework for nonadiabatic transitions was developed independently by Lev Landau and Clarence Zener in 1932, along with contributions from Ernst Stueckelberg. Their work laid the foundation for understanding quantum dynamics in rapidly changing environments.
When a parameter (such as an external magnetic field or molecular geometry) changes quickly, the system's state cannot adjust smoothly to remain in the same eigenstate. Instead, the wavefunction mixes with other eigenstates, leading to a probability of transitioning to a different energy level. The probability of such a transition is often described by the Landau-Zener formula, which depends on the speed of the parameter change and the energy gap between levels.
Nonadiabatic transitions are exploited in quantum control techniques, such as rapid adiabatic passage and stimulated Raman adiabatic passage, and are also relevant in molecular physics for understanding chemical reaction dynamics and in spintronics for manipulating electron spins.
The Landau-Zener formula, which describes nonadiabatic transition probabilities, is so general that it applies not only to quantum systems but also to classical wave propagation in slowly varying media, such as light passing through a chirped grating.
















